Page 35 - Industrial Plants
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development and deployment.               this chemical process can be   “In addition to the available
            As the availability of bio-derived SAF is limited, since   carried out in very small   technologies, ‘Short contact
            agricultural areas should be dedicated to food   reactors having a very high   time catalytic partial oxidation’
            production, the main contribution to SAF/e-fuel   flexibility towards reactant   (SCT-CPO) represents the most
            production  in  the  future  will  have  to  come  from  the   types and flow variations.  innovative one, based on a
            production  of  synthetic  fuels,  which  is  processed  in   It has also been found that   very fast catalytic reaction
            two-steps:                                several    hydrocarbon   that allows contact times
            •   the  generation of  synthesis  gas,  possibly  from   feedstocks, even containing   between reagents 10,000 –
                low-carbon feedstocks (like methane, waste   sulphur  and  aromatic  50,000 times shorter than
                gases, etc.) integrating also renewable hydrogen   compounds, can be fed to a   the ones of traditional
                and captured CO ; 2                   SCT-CPO   reactor  for    catalytic processes for
            •   a fuel synthesis section, where synthesis gas is   producing synthesis gas.   the production of hydrogen
                transformed into a synthetic liquid fuel, equivalent   A long-term R&D effort is
                to traditional fossil fuels; Liquid methanol from   driving  towards  the
                methanol synthesis (2) and Liquid hydrocarbons   industrialization phase of a technology whose main
                from Fischer-Tropsch synthesis are the main   advantages concern:
                options.                              •   Reduction of investment costs and energy
            Currently, SAF  production is energy and capital   consumption;
            intensive and to support the required learning curve for   •   Reduction of  overall  CO  production and
                                                                              2
            the 2050 targets, it is necessary to invest in scaling up   possibility of an almost complete CO  capture for
                                                                                   2
            production technologies to industrial maturity that may   the generation of Blue Hydrogen;
            leverage  on  largely available feedstocks with high   •   Flexibility towards feedstock composition &
            efficiency and minimum CO  emission.         production capacity.
                                2
                                                        “Several hydrocarbon feedstocks,
                                                      even containing sulphur and aromatic
            SCT-CPO: an innovative,                   compounds, can be fed to a SCT-CPO
            scalable and low carbon                    reactor for producing synthesis gas

            emission process                          Leveraging on multidisciplinary engineering capabilities
                                                      and 30 years of experience in integrating technologies
            The most utilized synthesis gas production processes   and systems in compact layout and robust design for
            are:                                      offshore  operations,  Fores  Engineering  (Fores)  has
            •   Steam reforming (SR);                 contributed to the industrial scale-up of the innovative
            •   Partial oxidation (Pox);              CPO technology with 3 different plant references
            •   Autothermal reforming (ATR).          (designed, built and commissioned), each one
            In addition to the available listed technologies, “Short   addressing different challenges:
            contact time catalytic partial oxidation” (SCT-CPO)   •   Small dimensions with technical and operational
            represents the most innovative one, based on a very   simplicity;
            fast catalytic reaction that allows contact times   •   Possibility of modular construction of prefabricated
            between reagents (hydrocarbon, steam, air/oxygen)   and skid-mounted units;
            10.000 – 50.000  times shorter than the ones of   •   Specific tailor-made design solutions (Mega
            traditional catalytic processes for the production of   Syngascooler) on  large industrial scale
            hydrogen. The fast and selective  chemistry of the   applications.
            process  is  confined inside a  thin  (<1 mm) solid–gas
            inter-phase  zone  surrounding  the  catalyst  particles;
            here, the gas molecules spend a limited time (10-6
            seconds) at  temperatures variable between 600  –  The first pilot plant with SCT-CPO
            1200° C, while avoiding the propagation of reactions   technology for the production of
            into the gas phase, that has to remain at a “relatively
            low” temperature.                         hydrogen (Milazzo 2004/ 2005)
            This condition favours the formation of primary reaction
            products (namely CO and H2) inhibiting chain reactions.   Fores has successfully accomplished the design and
            Moreover, the very high catalytic surface temperatures   construction of a first pilot plant through a Lump Sum
            inhibit its deactivation phenomena related to chemical   Turnkey (LSTK) contract, starting from a conceptual
            poisoning effects. For these and other related reasons,   engineering developed by ENI (client & IP owner of the

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