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Saipem is a leading licensor of urea                    considered a leader in urea plant design, thanks
                                                 technology through its proprietary     to its ability to channel all of that knowledge into
                                                 SnamprogettiTM technology, as well as  its proprietary know-how, which it applies to study
                                                 a worldwide leader in designing and    and develop innovative new solutions.
                                                 building ammonia/urea complexes.       This approach to urea technology is the driver
                                                 With over 130 existing SnamprogettiTM  behind a significant research and development
                                 Urea Technology licenses in 34 countries (mainly       effort on the part of the company, which sees
                                 India and China) and a daily urea production           special attention paid to studies aimed at identifying
                                 exceeding 235,000 metric tons, Saipem holds            new and efficient process solutions.
                                 more than one third of worldwide installed urea        The results of this effort have recently led to the
                                 capacity and has also licensed one of the world’s      development of two new innovations that look set to
                                 largest single urea line plants, the Wulan Plant in    secure an important role for the SnamprogettiTM on
                                 China, with a production capacity of 4,000 tons per    future urea/ammonia projects, namely Supercups
                                 day.                                                   trays and Omegabond® Technology.

                                HP loop development: two                                Supercups trays
                                innovative solutions for urea                           for urea reactor
                                reactors and urea strippers
                                                                                        Urea reactors are non-ideal multi-phase plug-
                                An old saying goes: “knowledge is born from
                                experience”. So what kind of experience is required     flow reactors (PFR) type equipped with dedicated
                                to be able to tackle all the various aspects of an
                                innovative chemical plant technology? In answering      distributors for the reagents and a number of sieve
                                this question, we need to bear in mind that the
                                extent of knowledge in the various disciplines          type trays, consisting of perforated plates that
                                pertaining to the design, management and start-
                                up of a fertilizer plant is enormous; whereas           prevent back-flow of the heavier solution from
                                what is commonly referred to as “technology” is
                                a very specific, minor part - albeit one of central     the upper part downwards and that favour gas
                                importance. In other words, the experience
                                acquired in all of those various aspects constitutes    absorption in the liquid phase.
                                a key factor in achieving excellence.
                                In this framework Saipem, with its proprietary          The innovative concept of the Snamprogetti™
                                technology SnamprogettiTM Urea, can be
                                                                                        SuperCups lies in the realization of a confined

                                                                                        reaction space within the reactor tray geometry,

                                                                                        in the form of the cups themselves, which provide

                                                                                        mixing units in which ammonia is contacted with

Urea plant view                                                                         tOhnecgeastheeouresaCcOta2nitns  small  bubbles.        the  cups,
                                                                                                                         have   swirled inside

                                                                                        the mixed solution of product and non-reacted

                                                                                        components is uniformly distributed on the upper

                                                                                        part of the tray by means of the upper cup

                                                                                        distributor. The outlet flow pattern ensures

                                                                                        a further mixing of the solution coming from

                                                                                        all the cups.

                                                                                        The behavior of the SuperCups is

                                                                                        characterized by a triple fluid-dynamic

                                                                                        effect: Gas Equalizer, Mixer Reactor and Gas

                                                                                        Distributor (figure 1).

                                                                                        The SuperCups technology was

                                                                                        comprehensively tested in two industrial

                                                                                        facilities and is now ready for commercial

                                                                                        launch.

                                                                                        The performance of these innovative trays

                                                                                        was assessed by monitoring plant operation

                                                                                        over a wide time frame. The laboratory

                                                                                        analyses, the steam balance and the process

                                                                                        evaluation of each process section all

                                                                                        provided evidence of an enhancement in the

                                                                                        performance of the units in question which,

                                                                                        following installation of the SuperCups,

                                                                                        operated at increased plant loads with

                                                                                        higher reactor yield and lower specific energy

                                                                                        consumption. In addition, at maximum plant

                                                                                        capacities - where reactor volume becomes

                                                                                        a limiting factor - the improvement in fluid-

Fig. 1 - CFD of SuperCups tray                                                          dynamic patterns afforded by SuperCups

                                                                                        Impiantistica Italiana - Luglio-Agosto 2016 69
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