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NEW TRENDS







































       Figure 3 - Scheme of Green Hydrogen Project in Middle East.


                            the sea, water scarcity quickly became a critical   hydrocarbons, fi ne suspended solids, heavy metals
                            issue.                                    and other pollutants.
                            The scope of the study, summarized in Figure 3,   Bridging the gap between the inlet streams com-
                            was a 2.5 MW Electrolyzer, designed to produce 1   position and the required quality at Electrolyzer
                            ton of hydrogen per day, and its ancillaries.  feed was not an easy task, as hinted by the water
                                                                      analysis in Table 1.
                            One of the pillars of such a scheme was the availa-  Leveraging an extensive track record in produced
                            bility of 10 m /day of ultrapure demineralized water.   water treatment and effl uent reuse on one side,
                                      3
                            This is not a huge water demand, but in a desert   and on ion removal up to the part per billion level
                            environment every drop counts, and the only avai-  on the other, Cannon Artes designed a customized
                            lable source of clean water was a limited amount of   solution to the water problem; once the technical
                            highly saline well water that, alone and at the net of   side of the equation was solved, a detailed CAPEX
                            processing losses, could not satisfy the demand.   and OPEX budget was defi ned as input for io con-
                                                                      sulting’s master study.
                            A second, unusual source of water was identifi ed in   The resulting water treatment plant’s process, de-
                            the produced water effl uent from a nearby oilfi eld:   picted in Figure 4, can be divided into three sec-
                            produced water is the formation water that gets ex-  tion: Pre-treatment, Ion-removal and fi nal Polishing.
                            tracted together with crude oil and represents one
                            of the major waste streams in oilfi elds by volume,   The Pre-treatment section is functional to achie-
                            and one that needs highly specialized expertise   ving, for each water source, a suitable quality for
       Table 1 - Summary of inlet   and technologies for its disposal or reuse, due to   the downstream treatment: the process is straight-
       and outlet water analysis.  the high salinity and presence of large quantities of   forward for the well water stream, while it is extre-

                                                                                               Demi water
                                                          Produced Water      Well water
                                                Unit                                        ASTM D1193-91 -
                                                               Inlet            Inlet
                                                                                                 Type I
                                             3
                Flowrate                    m /day             20.0             10.0              10.0
                Conductivity                µS/cm            132’100           39’500            < 0.056
                Total Dissolved Solids      mg/l             102’000           26’500            < 5 ppb
                Chloride                    mg/l              63’100           15’500            < 1 ppb
                Sodium                      mg/l              30’900            6’790            < 1 ppb
                Total Suspended Solids      mg/l               180               25               Nihil


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