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Figure 5. Effect of the H content (0.2 - 10 mol.%) on the density (left) and Higher Wobbe Index (right) of natural gas
2
rent temperatures is better estimated by means of the Boiling Point of Normal Hydrogen as a Basic Point in Ther-
MBWR EoS, fundamental EoSs developed ad-hoc for mometry. Commun. Kamerlingh Onnes Lab. Univ. Leiden
24
the specific pure component, like the one presented (217A), 1-9.
by Leachman et al. , or the ZJ EoS. The latter ther- 11. Scott, R., Brickwedde, F., Urey, H.C., Wahl, M., 1934. The
20
1
modynamic model has proved to work well also in pre- vapor pressures and derived thermal properties of hydro-
dicting vapor-liquid equilibrium data for the binary system gen and deuterium. The Journal of Chemical Physics 2(8),
hydrogen + methane, which deserves attention conside- 454-464.
ring the numerous recent studies on the hydrogen use in 12. Aston, J., Willihnganz, E., Messerly, G.H., 1935. Heat Ca-
the natural gas distribution system. pacities and Entropies of Organic Compounds. I. A Ther-
modynamic Temperature Scale in Terms of the Copper-
References Constantan Thermocouple from 12 to 273° K. Journal of
the American Chemical Society 57(9), 1642-1646.
1. Leachman, J.W., Jacobsen, R.T., Penoncello, S., Lemmon, 13. White, D., Friedman, A.S., Johnston, H.L., 1950. The Va-
E.W., 2009. Fundamental equations of state for parahydro- por Pressure of Normal Hydrogen from the Boiling Point to
gen, normal hydrogen, and orthohydrogen. Journal of the Critical Point. Journal of the American Chemical Society
Physical and Chemical Reference Data 38(3), 721-748. 72(9), 3927-3930.
2. Verfondern, K., 2008. Safety consideration on liquid hydro- 14. Grilly, E., 1951. The Vapor Pressures of Hydrogen, Deute-
gen. rium and Tritium up to Three Atmospheres. Journal of the
3. Bonhoeffer, K.F., Harteck, P., 1929. Über Para- und Or- American Chemical Society 73(2), 843-846.
thowasserstoff. Zeitschrift für Physikalische Chemie 4B(1), 15. Van Itterbeek, A., Verbeke, O., Theewes, F., Staes, K., De
113-141. Boelpaep, J., 1964. The difference in vapour pressure
4. Harkness, R.W., Deming, W.E., 1932. The equilibrium of between normal and equilibrium hydrogen. Vapour pres-
para and ortho hydrogen. Journal of the American Chemi- sure of normal hydrogen between 20 K and 32 K. Physica
cal Society 54(7), 2850-2852. 30(6), 1238-1244.
5. Hoge, H.J., Arnold, R.D., 1951. Vapor pressures of hydro- 16. Streett, W., Jones, C., 1965. Liquid phase separation and
gen, deuterium, and hydrogen deuteride and dew-point liquid-vapor equilibrium in the system neon-hydrogen. The
pressures of their mixtures. Journal of Research of the Na- Journal of Chemical Physics 42(11), 3989-3994.
tional Bureau of Standards 47(2), 63-74. 17. Peng, D.-Y., Robinson, D.B., 1976. A new two-constant
6. Barber, C., Horsford, A., 1963. The determination of the equation of state. Industrial & Engineering Chemistry Fun-
boiling and triple points of equilibrium hydrogen and its va- damentals 15(1), 59-64.
pour pressure-temperature relation. British Journal of Ap- 18. Soave, G., 1972. Equilibrium constants from a modified
plied Physics 14(12), 920-923. Redlich-Kwong equation of state. Chemical Engineering
7. Travers, M., Jaquerod, A., Senter, G., 1902. Part I. Pres- Science 27(6), 1197-1203.
sure Coefficients of Hydrogen and Helium; Part II. Vapour 19. Stryjek, R., Vera, J., 1986. PRSV—An improved Peng-Ro-
Pressures of Liquid Oxygen; Part III. Vapour Pressures of binson equation of state with new mixing rules for strongly
Liquid Hydrogen. Proceedings of the Royal Society of Lon- nonideal mixtures. The Canadian Journal of Chemical Engi-
don, 484-491. neering 64(2), 334-340.
8. Cath, P., Crommelin, C., Onnes, H.K. In: Isothermals of di- 20. Zudkevitch, D., Joffe, J., 1970. Correlation and prediction
atomic substances and their binary mixtures. XIX. A prelimi- of vapor-liquid equilibria with the Redlich-Kwong equation
nary determination of the critical point of hydrogen, KNAW, of state. AIChE Journal 16(1), 112-119.
Proceedings, 1918; pp. 178-184. 21. Jacobsen, R.T., Stewart, R.B., 1973. Thermodynamic pro-
9. Henning, F., 1927. Tensions-und Widerstandsthermometer perties of nitrogen including liquid and vapor phases from
im Temperaturgebiet des verflüssigten Stickstoffs und Wa- 63K to 2000K with pressures to 10,000 bar. Journal of
sserstoffs. Zeitschrift für Physik 40(10), 775-785. Physical and Chemical Reference Data 2(4), 757-922.
10. Keesom, W., Bijl, A., van der Horst, H., 1931. Determina- 22. Gunn, R., Chueh, P., Prausnitz, J., 1966. Prediction of ther-
tion of the Boiling Points and the Vapour-Pressure Curves modynamic properties of dense gas mixtures containing one
of Normal Hydrogen and of Para-Hydrogen. The Normal or more of the quantum gases. AIChE Journal 12(5), 937-941.
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